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  • 03Nov
    Vis_mao_duan_2009gAbstract An accurate viscosity (dynamic viscosity) model is developed for aqueous

    Abstract

    alkali-chloride solutions of the binary systems, LiCl–H2O, NaCl–H2O, and KCl–
    H2O, from 273K to 623 K, and from 1 bar to 1,000 bar and up to high ionic strength.
    The valid ionic strengths for the LiCl–H2O, NaCl–H2O, and KCl–H2O systems are
    0 to 16.7mol · kg−1, 0 to 6mol · kg−1, and 0 to 4.5 mol · kg−1, respectively. Comparison
    of the model with about 4,150 experimental data points concludes that the
    average absolute viscosity deviation from experimental data in the above range is
    within or about 1 % for the LiCl–H2O, NaCl–H2O, and KCl–H2O mixtures, indicating
    the model is of experimental accuracy. With a simple mixing rule, this model can
    be extrapolated to predict the viscosity of ternary aqueous alkali-chloride solutions,
    making it useful in reservoir fluid flow simulation. A computer code is developed for
    this model and can be obtained from the author: (maoshide@cugb.edu.cn).An accurate viscosity (dynamic viscosity) model is developed for aqueous
    alkali-chloride solutions of the binary systems, LiCl–H2O, NaCl–H2O, and KCl–
    H2O, from 273K to 623 K, and from 1 bar to 1,000 bar and up to high ionic strength.
    The valid ionic strengths for the LiCl–H2O, NaCl–H2O, and KCl–H2O systems are
    0 to 16.7mol · kg−1, 0 to 6mol · kg−1, and 0 to 4.5 mol · kg−1, respectively. Comparison
    of the model with about 4,150 experimental data points concludes that the
    average absolute viscosity deviation from experimental data in the above range is
    within or about 1 % for the LiCl–H2O, NaCl–H2O, and KCl–H2O mixtures, indicating
    the model is of experimental accuracy. With a simple mixing rule, this model can
    be extrapolated to predict the viscosity of ternary aqueous alkali-chloride solutions,
    making it useful in reservoir fluid flow simulation. A computer code is developed for
    this model and can be obtained from the author: (maoshide@cugb.edu.cn)Abstract An accurate viscosity (dynamic viscosity) model is developed for aqueous
    alkali-chloride solutions of the binary systems, LiCl–H2O, NaCl–H2O, and KCl–
    H2O, from 273K to 623 K, and from 1 bar to 1,000 bar and up to high ionic strength.
    The valid ionic strengths for the LiCl–H2O, NaCl–H2O, and KCl–H2O systems are
    0 to 16.7mol · kg−1, 0 to 6mol · kg−1, and 0 to 4.5 mol · kg−1, respectively. Comparison
    of the model with about 4,150 experimental data points concludes that the
    average absolute viscosity deviation from experimental data in the above range is
    within or about 1 % for the LiCl–H2O, NaCl–H2O, and KCl–H2O mixtures, indicating
    the model is of experimental accuracy. With a simple mixing rule, this model can
    be extrapolated to predict the viscosity of ternary aqueous alkali-chloride solutions,
    making it useful in reservoir fluid flow simulation. A computer code is developed for
    this model and can be obtained from the author: (maoshide@cugb.edu.cn).

    An accurate viscosity (dynamic viscosity) model is developed for aqueous
    alkali-chloride solutions of the binary systems, LiCl–H2O, NaCl–H2O, and KCl–
    H2O, from 273K to 623 K, and from 1 bar to 1,000 bar and up to high ionic strength.
    The valid ionic strengths for the LiCl–H2O, NaCl–H2O, and KCl–H2O systems are
    0 to 16.7mol · kg−1, 0 to 6mol · kg−1, and 0 to 4.5 mol · kg−1, respectively. Comparison
    of the model with about 4,150 experimental data points concludes that the
    average absolute viscosity deviation from experimental data in the above range is
    within or about 1 % for the LiCl–H2O, NaCl–H2O, and KCl–H2O mixtures, indicating
    the model is of experimental accuracy. With a simple mixing rule, this model can
    be extrapolated to predict the viscosity of ternary aqueous alkali-chloride solutions,
    making it useful in reservoir fluid flow simulation. A computer code is developed for
    this model and can be obtained from the author: (maoshide@cugb.edu.cn).

  • 15Sep

    Shide Mao, Zhenhao Duan and Wenxuan Hu(2009) A vapor–liquid phase equilibrium model for binary CO2–H2O and CH4–H2O systems above 523K for application to fluid inclusions.The Journal of Supercritical Fluids, 50 (2009): 13-21.60-JSF-2009-50-13

  • 15Sep

    Chi Zhang and Zhenhao Duan. (2009) A model for C-O-H fluid in the Earth’s mantle .Geochimica et Cosmochimica Acta., 73 (7): 2089-2102.

  • 15Sep

    Mingyan Li,Zhenhao Duan, Zhigang Zhang,Chi Zhang & John Weare (2008) The structure, dynamics and solvation mechanisms of ions in water from long time molecular dynamics simulations: a case study of CaCl2 (aq) aqueous solutions.Molecular Physics, 106 (24): 2685-2697.

  • 15Sep

    Zhenhao Duan , Dedong Li (2008) Coupled phase and aqueous species equilibrium of the H2O–CO2–NaCl–CaCO3 system from 0 to 250 C, 1 to 1000 bar with NaCl concentrations up to saturation of halite. Geochim. Cosmochim. Acta, 72 (20): 5128-5145.

  • 15Sep

    Qin JF, Rosenbauer RJ, and Duan ZH. (2008) Experimental Measurements of Vapor-Liquid Equilibria of the H2O+CO2+CH4 Ternary System.Journal of Chemical & Engineering Data., 53 (6): 1246-1249.

  • 15Sep

    Mao SD, and Duan ZH, (2008) The P, V, T,x properties of binary aqueous chloride solutions up to T = 573 K and 100 MPa. The Journal of Chemical Thermodynamics., 40 (7): 1046-1063.

  • 15Sep

    Duan ZH, Hu JW, Li DD and Mao SD. (2008) Densities of the CO2-H2O and CO2-H2O-NaCl Systems Up to 647 K and 100 MPa.Energy & Fuels., 22 (3): 1666-1674.

  • 15Sep

    Li DD, and Duan ZH, (2007) The speciation equilibrium coupling with phase equilibrium in the H2O-CO2-NaCl system from 0 to 250 °C, from 0 to 1000 bar and from 0 to 5 molality of NaCl. Chemical Geology., 244 (3-4): 730-751.

  • 15Sep

    Sun R, and Duan ZH, (2007) An Accurate Model to predict the Thermodynamic Stability of Methane Hydrate and Methane Solubility in Marine Environments. Chemical Geology., 244 (1-2): 248-262.

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